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  • Received: Feb. 8, 2020

    Accepted: May. 15, 2020

    Posted: Jul. 20, 2020

    Published Online: Jul. 22, 2020

    The Author Email: Qinghui Li (qinghuil@sina.com)

    DOI: 10.3788/COL202018.090001

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    Junqing Dong, Qinghui Li, Yongqing Hu. Multi-technique analysis of an ancient stratified glass eye bead by OCT, μ-XRF, and μ-Raman spectroscopy[J]. Chinese Optics Letters, 2020, 18(9): 090001

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Chinese Optics Letters, Vol. 18, Issue 9, 090001 (2020)

Multi-technique analysis of an ancient stratified glass eye bead by OCT, μ-XRF, and μ-Raman spectroscopy

Junqing Dong1,2, Qinghui Li1,2,*, and Yongqing Hu3

Author Affiliations

  • 1Sci-Tech Archaeology Center, Laboratory of Micro-Nano Optoelectronic Materials and Devices, Key Laboratory of Materials for High-Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • 3Henan Provincial Institute of Cultural Relics and Archaeology, Zhengzhou 450000, China

Abstract

In this Letter, we report a combination of non-invasive analysis of the cross-section structure, phase, and chemical composition combining optical coherence tomography (OCT) with spectroscopic methods such as X-ray analytical microscope (μ-XRF) and micro-Raman spectroscopy (μ-RS), which allow us to effectively and conveniently identify the colorants used for each color region and the glass-making process of an ancient multicolored stratified glass eye bead. The results reveal that the sophisticated colors of the glass bead arise from the transition metals and chemical compound crystals deliberately added in the same base glass and carefully adjusted by the glass maker to obtain four colors. We also propose and discuss the provenance of the glass bead. It was probably introduced to China through the Northern Silk Road from Egypt or the Eastern Mediterranean areas about 1400 years ago. The combined multi-analytical technique is the promising approach for precious cultural heritage research.

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